생무기화학 실험실
생무기화학 실험실
 학과소개 연구실/실험실 생무기화학 실험실
담당교수 김 철 교수
연구분야 무기화학, 생무기화학, 무기의약품, 인공광합성
분야설명 원자 및 분자의 구조, 물질의 결합, 스펙트럼, 자성,구조, 산염기화학 등의 이론을 실습을 통하여 체계화하고 실험에서 합성한 물질을 기기을 통하여 분석할 수 있는 능력을 기른다.
- 생체 모방 인공 효소 개발(biomimetic study)
- 무기 의약품 개발(inorganic medicine)
- 생리 활성 금속 이온 검출을 위한 센서 개발(sensors for biological metal ions)
- 산양삼을 활용한 건강식품 개발
- 수소 저장을 위한 폴리머 개발
- 가죽에 포함되어 있는 항생제 추적
- carbon dioxide 저장을 위한 인공광합성 시스템 개발
논문 및 저서
  • - “Evidence for the participation of two distinct reactive intermediates in iron(III) porphyrin complex-catalyzed epoxidation reactions” J. Am. Chem. Soc. 2000, 122, 6641-6647.
  • - “First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrin complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrin complxes in aprotic solvent” J. Inorg. Biochem. 2000, 80, 219-225.
  • - “New insights into the mechanism of O-O bond cleavage of hydrogen peroxide and tert-alkyl hydroperoxides by iron(III) porphyrin complexes” J. Am. Chem. Soc. 2000, 122, 8677-8684.
  • - “Remarkable anionic axial ligand effects of iron(III) porphyrin complexes on the catalytic oxygenation of hydrocarbons by H2O2 and the formation of oxoiron(IV) porphyrin intermediates by m-chloroperoxybenzoic acid” Angew. Chem. Int. Ed. 2000, 39, 3646-3649.
  • - “Participation of two distinct hydroxylating intermediates in iron(III) porphyrin complex-catalyzed hydroxylation of alkanes” J. Am. Chem. Soc. 2000, 122, 10805-10809.
  • - “Electronic effect of iron(III) porphyrin complexes on the epoxidation of cyclohexene: epoxidation versus hydroxylation” Bull. Korean Chem. Soc. 2001, 22, 1-4.
  • - “Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid” Chem. Commun. 2001, 1262-1263.
  • - “Design and properties of mixed-metal multinuclear molecules” Polyhedron 2002, 21, 33-37.
  • - “Biomimetic alcohol oxidations by an iron(III) porphyrin complex: relevance to cytochrome P-450 catalytic oxidation and involvement of the two-state radical rebound mechanism” Dalton Trans. 2005, 402-406.
  • - “Simultaneous binding of meso-tetrakis(N-methylpyridinium-4-yl)porphyrin and 4’,6-diamidino-2-phenylindole at the minor grooves of poly(dA).poly(dT) and poly[d(A-T)2]: Fluorescence resonance energy transfer between DNA bound drugs” J. Am. Chem. Soc. 2005, 127, 2417-2424.
  • - “Crystal structure of 1,2-bis(2-pyrazinecarboxamido)-4,5-dimethylbenzene” Analytical Sciences 2005, 21, x23-x24.
  • - “Crystal structure of [(1,2-bis(2-pyridine-2-carboxamido)-4,5-dimethylbenzene)(dipyridine)] cobalt(III) perchlorate” Analytical Sciences 2005, 21, x39-x40.
  • - “Self-assembly coordination compounds of Cu(II), Zn(II), and Ag(I) with btp ligands (btp = 2,6-bis(N’-1,2,4-triazolyl)pyridine): counteranion effects” Korean J. Crystallography 2005, 16, 107-127.
  • - “Crystal structure of one-dimensional [ZnCl2(N2C12H12)]n (N2C12H12 = 1,2-bis(4-pyridyl)ethane)” Analytical Sciences 2005, 21, x65-x66.
  • - “The two-dimensional structure of poly[diperchloratocopper(II)]-bis[u2-1,3-bis(4-pyridyl)propane]” Acta Crystallographica E 2005, E61, m1489-m1491.
  • - “catena-Poly[[dibromozinc(II)]-u-1,2-bis(4-pyridyl)ethane], a one-dimensionak coordination polyner” Acta Crystallographica E 2005, E61, m1561-m1562.
  • - “Novel infinite hexanuclear zinc coordination polymer with a flexible bipyridyl ligand and its catalytic activity” Inorg. Chem. Commun. 2005, 8, 692-696.
  • - “Syntheses and structures of Ag(I) compounds containing btp ligands” Inorg. Chim. Acta 2005, 358, 3398-3406.
  • - “Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO3)2 and Cu(H2O)22+ units bridged alternatively by btp ligands (btp=2,6-bis(N’-1,2,4-triazolyl)pyridine)” J. Mol. Struct. 2005, 751, 22-28.
  • - “Crystal structures and catalytic activities of Zn(II) compounds containing btp ligands” Inorg. Chim. Acta 2005, 358, 3659-3670
  • - “Conversion of epoxides into trans-diols or trans-diol mono-ethers by iron(III) porphyrin complex” Bull. Korean Chem. Soc. 2005, 26, 1434-1436.
  • - “Construction of an interpenetrated 3-D network by [2+2] cycloaddition of Zn(ClO4)2 and 1,2-trans-(4-pyridyl)ethene: counter anion effect” Dalton Trans. 2005, 3716-3718.
  • - “Crystal structure of one-dimensional [ZnCl2(N2C13H14)]n (N2C13H14 = 1,3-bis(4-pyridyl)propane)” Analytical Sciences 2005, 21, x203-x204.
  • - “Norbornene and ethylene polymerization with palladium and nickel complexes with potentially tri- or tetradentate ligands” Studies in Surface Science and Catalysis 2006, 161, 59-68.
  • - “4,5-Dimethyl-1,2-bis(quinoline-2-carboxamido)benzene” Acta Crystallographica E, 2006, E62, o1189-o1191.
  • - “Crystal structure of 1,2-bis(6-methylpyridine-2-carboxamido)-4,5-dimethylbenzene” Analytical Sciences 2006, 22, x37-x38.
  • - “Crystal structures and catalytic activities of Zn(II) compounds containing 1,3-bis(4-pyridyl)propane” Inorg. Chim. Acta 2006, 359, 2534-2542.
  • - “Efficient transesterification by polymer-supported zinc complexes: clean and recyclable catalysts” Inorg. Chem. Commun. 2006, 9, 658-661.
  • - “Crystal structure of a coordination polymer cation of {[Ni(NO3)(H2O)(btp)]+} bridged by two btp ligands (btp=2,6-bis(N’-1,2,4-triazolyl)pyridine)” Analytical Sciences 2006, 22, x141-x142.
  • - “Tetraethylammonium dichloro[N,N’-(4,5-dichloro-1,2-phenylene)bis-(pyridine-2-carboxamidato)] chromate(III)” Acta Crystallographica E 2006, E62, m2715-m2716.
  • - “Urea/thiourea-based colorimetric chemosensors for the biologically important ions: efficient and simple sensors” Tetrahedron 2006, 62, 9635-9640.
  • - “Novelnickel catalysts containing tetradentate chelating ligands for the polymerization of norbornene” Bull. Korean Chem. Soc. 2006, 27, 1031-1037.
  • - “[Diaqua-bis(2,6-(N’-1,2,4-triazolyl)pyridinato)trinitrate]lathanum(III) monohydrate” Acta Crystallographica E 2007, E63, m269-m271.
  • - “Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2’-dipyridylamine (Hdpa): novel heterogeneous catalytic activities” Inorg. Chem. Commun. 2007, 10, 287-291.
  • - “Structure and catalytic activity of a hexarhenium cluster-supported copper cubanes [{Cu4(m-OH)(NH3)7}2{Re6Se8(CN)6}][Re6Se8(CN)6]2H2O” Inorg. Chem. Commun. 2007, 10, 586-589.
  • - “Pd(II) polymeric compounds directed by intermolecular C-H--X-C interactions (X=F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex” Polyhedron 2007, 26, 1388-1396.
  • - “N,N’-(4,5-Dichloro-o-phenylene)dibenzamide” Acta Crystallographica E 2007, E63, o0341.
  • - “Tetraethylammonium dichloride[N,N’-(o-phenylene)bis(isoquinoline-2-carboxamidato)-k4N]cobaltate(III)” Acta Crystallographica E 2007, E63, m1949-m1950
  • - “Novel polymer-supported ruthenium and iron complexes that catalyze the conversion of epoxides into diols or diol mono-ethers: clean and recyclable catalysts” New J. Chem. 2007, 31, 1579-1582.
  • - “4,5-Dimethyl-1,2-bis(pyridine-3-carboxamido)benzene” Acta Crystallographica E 2007, E63, o4104-o4105.
  • - “Biomimetic hydrocarbon oxidation catalyzed by nonheme iron(III) complexes with peracids: evidence for an Fev=O species” Chem. Eur. J. 2007, 13, 9393-9398.
  • - “Tetra-m-benzoato-bis[(quinoxaline)copper(II)]” Acta Crystallographica E 2008, E64, m286.
  • - “Construction of Zn(II) compounds with a chelating ligand 2,2’-dipyridylamine (Hdpa): anion effect and catalytic activities” Eur. J. Inorg. Chem. 2008, 408-415.
  • - “Bis(2,6-dimethylpyrazine-kN4)diiodidozinc(II)” Acta Crystallographica E 2008, E64, m511.
  • - “Synthesis, structure, and heterogeneous catalytic activity of tungsten chalcogenide cubane cluster containing alkaline earth metal complex” Inorg. Chim. Acta 2008, 361, 1885-1890.
  • - “Tetra-m-benzoato-bis[(6-methylquinoline)copper(II)]” Acta Crystallographica E 2008, E64, m881-m882.
  • - “Tetra-m-benzoato-bis[(3-methylquinoline)copper(II)](Cu-Cu)” Acta Crystallographica E 2008, E64, m1141.
  • - “Steric effect on construction of Cu(II) complexes with pyridine carboxamide ligands” J. Mol. Struct. 2008, 885, 56-63
  • - “Zn(II) polymeric compounds with a chelating ligand bis(2-pyridylmethyl)amine (bispicam) directed by intermolecular C/N/O-H---X (X=Cl, Br, I) interactions: catalytic activities” J. Mol. Struct. 2008,890, 123-129.
  • - “Substituent effects of pyrazine on construction of crystal structures of Zn(II) benzoate complexes and their catalytic activities (dinuclear, trinuclear, and pentanuclear to 1-D and 2-D)” Polyhedron 2008, 27, 3484-3492.
  • - “Controlling self-assembly of zinc(II)-benzoate coordination complexes with 1,4-bis(4-pyridyl)ethane by varying solvent and ligand-to-metal ratio: Their catalytic activities” Polyhedron 2009, 28, 553-561.
  • - “Metal-directed supramolecular assembly of metal(II) benzoates (M = Co, Ni, Cu, Zn, Mn, and Cd) with 4,4-bipyridine: Effects of metal coordination modes and novel catalytic activities” Polyhedron 2009, 28, 1241-1252.
  • - “A neutral cubane with a ZnII4O4 core: tetrabenzoatotetrakis(m3-hydroxydi-2-pyridylmethanolato)tetrazinc(II)-acetone-methanol (1/2/1)” Acta Crystallographica E 2009, E65, m658-m659.
  • - “Bis(di-2-pyridylmethanediol-k3N,O,N)nickel(II) dinitrate” Acta Crystallographica E 2009, E65, m678-m679. catena-Poly[[bis(2-hydroxy-2-phenylacetato-k2O1,O2)zinc(II)]-m-1,2-di-4-pyridylethane-k2N:N’]” Acta Crystallographica E 2009, E65, m1045-m1046.
  • - “Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities” Inorg. Chim. Acta 2009, 362, 4119-4126.
  • - *“High catalytic activities in the norbornene polymerization with neutral palladium complexes containing N4-type tetradentate chelating ligands” Inorg. Chim. Acta 2009, 362, 5097-5102.
  • - “Tetra-m-benzoato-bis{[trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene]zinc(II)}” Acta Crystallographica E 2009, E65, m1095-m1096.
  • - “Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M’(O2CPh)6](bpa) (M = Co, Zn, M’ = Co, Cd): their catalytic activity” Inorg. Chem. Commun. 2010, 13, 101-104.
  • - “Tetra-m-benzoato-bis{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}” Acta Crystallographica E 2010, E66, m61-m62
  • - “Construction of Cd(II) compounds with a chelating ligand 2,2-dipyridylamine (Hdpa): anion effect, catalytic activities and luminescence” Polyhedron 2010, 29, 773-786.
  • - “A naked-eye detection of fluoride with urea/thiourea receptors which have both a benzophenone group and a nitrophenyl group as a signaling group” Supramolecular Chemistry 2010, 22, 267-273.
  • - “Efficient Olefin Epoxidation by Robust Re4 Cluster-Supported MnIII Complexes with Peracids: Evidence of the Multiple Active Oxidants, MnV=O, MnIV=O, and MnIII-OO(O)CR Species, That Operate Simultaneously” Chemistry-A European Journal 2010, 16, 4687-4685.
  • - “Zinc citrate with alkali metal and ammonium cations: crystal structure of K4[Zn(citrate)2]” Journal of Structural Chemistry 2010, 51, 417-419.
  • - “Real-time detection of DNA cleavage induced by [M(2,2’-dipyridylamine)2(NO3)n]x+ (M= Cd, Cu, Ni, Zn, n=1,2, x=0,1) : Effect of central metal ions” Biophysical Chemistry 2010, 148, 138-143.
  • - “Two isomers containing a [Cu(Me2bpzb)] unit: molecule (0-D) and 1-D” Inorg. Chem. Commun. 2010, 13, 753-756.
  • - “Dibenzoatobis[3-(pyrrol-1-ylmethyl)pyridine]zinc(II)” Acta Crystallographica E 2010, E66, m980.
  • - “Bis(di-2-pyridylmethanediol-k3 N,O,N’)-nickel(II) dibenzoate” Acta Crystallographica E 2010, E66, m1281-m1282.
  • - “Steric effect on construction of Ni(II) polymeric compounds directed by intermolecular C-H···F and C-H···O interactions” Journal of Structural Chemistry 2010, 51, 923-930.
  • - “Construction, photoluminescence, and catalytic reactivity of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-dimensional looped chain” Inorganic Chemistry Communications 2010, 13, 1493-1496.
  • - “1-D, 2-D and 3-D Coordination polymers assembled from polynuclear CoII units based on isophthalate(-2) ligand” Polyhedron 2010, 29, 3335-3341.
  • - “Novel receptors with quinoline and amide moieties for the biologically important ions” Tetrahedron Letters 2010, 51, 6658-6662.
  • - “Poly[[bis[m-1,2-bis(4-pyridyl)ethane]bis(trichloroacetato)cadmium(II)]mono-hydrate]” Acta Crystallographica E 2011, E67, m3-m4
  • - “Anion effects on construction of ZnII compounds with a chelating ligand bis(2-pyridylmethyl)amine and their catalytic activities”Inorganica Chimica Acta 2011, 366, 337-343.
  • - “Simple urea/thiourea sensors for the biologically important ions” Journal of Inclusion of Macrocyclic and Phenonema 2011, in press.
  • - “Synthesis, crystal structures, photoluminescence, and catalytic reactivity of novel coordination polymers (0-D, 1-D to 2D) constructed from cis-1,2-cyclohexanedicarboxylic acid and various bipyridyl ligands” New Journal of Chemistry 2011, in press
  • - Robust and efficient amide-based nonheme manganese(III) hydrocarbon oxidation catalysts: substrate and solvent effects on involvement and partition of multiple active oxidants” Chemistry-A European Journal 2011, in revision.
  • - “Light-Induced Self-Assemblies Suitable for Photodimerization and Their Light-Induced [2 + 2] Cycloaddition: Light as a New Control Factor of Crystal Growth” Inorganica Chimica Acta 2011, submitted.
  • - “Steric and electronic effects of tetradentate Nickel(II) and Palladium(II) complexes toward the vinyl polymerization of norbornene” Journal of Organometallic Chemistry 2011, submitted.
  • - “Monomeric, Trimeric, and Tetrameric Transition Metal Complexes (Mn, Fe, Co) Containing N,N-Bis(2-pyridylmethyl)-2-aminoethanol/-ate: Preparation, Crystal Structure, Molecular Magnetism and Oxidation Catalysis” Dalton Transactions 2011, submitted.
  • - “Naked eye detection of fluoride and pyrophosphate with novel anion receptor utilizing anthracene and nitrophenyl group as signaling group” Journal of Organic Chemistry 2011, submitted.
  • - “Anion Effects on Crystal Structures of ZnII Complexes Containing 2,2’-bipyridine : Their Photoluminescence and Catalytic Activities” Polyhedron 2011, submitted.
  • - Anion effects on construction of ZnII compounds with a chelating ligand bis(2-pyridylmethyl)amine and their catalytic activities”Inorganica Chimica Acta 2011,366,337-343.
  • - catena-Poly[[tetraaqua[trans-1,2-bis(4-pyridyl)ethane-k2N:N’]nickel]dinitrate]” Acta Crystallographica E 2011,E67,m390.
  • - Synthesis, crystal structures, photoluminescence, and catalytic reactivity of novel coordination polymers (0-D, 1-D to 2D) constructed from cis-1,2-cyclohexanedicarboxylicacidandvariousbipyridylligands”NewJournalofChemistry2011,35,833-841
  • - Novel CdII coordination polymers (1-D, 2-D, to 3-D) constructed from 1,2-cyclohexanedicarboxylateand various bipyridyl ligands” JournalofMolecularStructure2011,994,335-342.
  • - Naked eye detection of fluoride and pyrophosphate with novel anion receptor utilizing anthracene and nitrophenyl group as signaling group” TetrahedronLetters2011,52,2759-2763.
  • - Monomeric, Trimeric, and Tetrameric Transition Metal Complexes (Mn, Fe, Co) Containing N,N-Bis(2-pyridylmethyl)-2-aminoethanol/-ate:Preparation,CrystalStructure,MolecularMagnetismandOxidationCatalysis”DaltonTransactions2011,40,5762-5773
  • - Anion Effects on Crystal Structures of ZnIIComplexesContaining2,2’-bipyridine:TheirPhotoluminescenceandCatalyticActivities”Polyhedron2011,30,1555-1564
  • - Simple urea/thiourea sensors for the biologically important ions” JournalofInclusionofMacrocyclicandPhenonema2011,70,29-35.
  • - Robust and efficient amide-based nonheme manganese(III) hydrocarbon oxidation catalysts: substrate an d solvent effects on involvement and partition of multiple active oxidants” Chemistry-A European Journal 2011,17,7336-7344.
  • - Steric and electronic effects of tetradentate Nickel(II) and Palladium(II) complexes toward the vinyl polymerization of norbornene” BulletinofKoreanChemicalSociety2011,32,1884-1890.
  • - Fine tuning of receptor polarity for the development of selective naked eye anion receptor” TetrahedronLetters2011,52,3361-3366. “Light-Induced Self-Assemblies Suitable for Photodimerization and Their Light-Induced [2 + 2] Cycloaddition: Light as a New Control Factor of Crystal Growth” Inorganica Chimica Acta 2011,inpress.
  • - Fluorescent chemosensor based-on naphthol-quinoline for selective detection of aluminum ions” TetrahedronLetters 2011,inrevision.
  • - Remarkable substituent effects on catalytic reactivities and generation of Co(V)=O species in olefin epoxidation by amide-based nonheme cobalt(III) complexes “ J.Am.Chem.Soc.2011,inrevision.
  • - Tuning structural topology of zinc(II)-benzoate coordination complexes with 1,4-bis(4-pyridyl)ethene by controlling metal-to-ligand ratios and solvent systems: Their photoluminescence and catalytic activities”Polyhedron 2011,submitted
  • - Selective Fe2+IonRecognitionUsingaFluorescentPyridinyl-benzoimidazole-derivedIonophore”DaltonTransactions 2011,submitted
  • - Zinc Selective Chemosensor Based on Pyridyl-amide Fluorescence” Tetrahedron2011,submitted.
특허
  • - Iron complexes for bleach activation and stereospecific oxidation, US Patet, 6, 107, 528, 2000. 8. 22.

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